Efficiency Enhancement of Wide Bandgap Lead Perovskite Solar Cells with PTAA Surface-Passivated with Monomolecular Layer from the Viewpoint of PTAA Band Bending

Huan Bi, Jiaqi Liu, Raminta Beresneviciute, Daiva Tavgeniene, Zheng Zhang, Liang Wang, Gaurav Kapil, Chao Ding, Shahrir Razey Sahamir, Yoshitaka Sanehira, Ajay Kumar Baranwal, Takeshi Kitamura, Dandan Wang, Yuyao Wei, Yongge Yang, Dong-Won Kang, Saulius Grigalevicius, Qing Shen, and Shuzi Hayase

ACS Applied Materials & Interfaces 2023 15 (35), 41549-41559

https://doi.org/10.1021/acsami.3c08655

This research focuses on enhancing the efficiency of wide bandgap lead halide perovskite solar cells (WBG Pb-PVK PSCs) using FA0.8Cs0.2PbI1.8Br1.2 as the light-harvesting layer. By passivating the hydrophobic surface of the hole transporting layer (PTAA) with a monomolecular layer, improved hydrophilicity and band alignment result in WBG Pb-PVK PSCs achieving an impressive 16.52% efficiency at 1.77 eV.

How Paios was used

MS curves, EIS, TPC, and TPV results were all performed using Paios from Fluxim

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Interfacial Engineering of a PCBM/AZO Electron Transport Bilayer for Efficient and Stable Inverted Perovskite Solar Cells

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Unraveling segregation behavior of inactive secondary phase driven by ion-competition reaction for perovskite-2D PbI2 heterojunction solar cells