Fluorinated Oligomer Wrapped Perovskite Crystals for Inverted MAPbI 3 Solar Cells with 21% Efficiency and Enhanced Stability

Xie, Lisha; Xie, Junni; Wang, Shurong; Chen, Bin; Yang, Chenguang; Wang, Zhen; et al.

ACS Appl. Mater. Interfaces 2021, 13, 22, 26093–26101

doi.org/10.1021/acsami.1c06216

In this paper the researchers report on a oligomer treatment of MAPI films which efficiently passivate defects by coordination with Pb ions. With additional improvements in crystallization and charge transport properties, the resulting cell had a PCE of 21.23% and showed better stability.

Paios was used to determine shorter TPC decay time and longer TPV lifetime was used to confirm the improved charge extraction properties.

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Tuning of the Interconnecting Layer for Monolithic Perovskite/ Organic Tandem Solar Cells with Record Efficiency Exceeding 21%

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Decoupling the effects of defects on efficiency and stability through phosphonates in stable halide perovskite solar cells